KEGG   REACTION: R05301
Entry
R05301                      Reaction                               
Name
penicillin-N,2-oxoglutarate:oxygen oxidoreductase (ring-expanding)
Definition
Penicillin N + 2-Oxoglutarate + Oxygen <=> Deacetoxycephalosporin C + Succinate + CO2 + H2O
Equation
C06564 + C00026 + C00007 <=> C06565 + C00042 + C00011 + C00001
Reaction class
RC01322  C06564_C06565
Enzyme
1.14.20.1
Pathway
rn00311  Penicillin and cephalosporin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00673  Cephamycin C biosynthesis, aminoadipate + cycteine + valine => cephamycin C
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.20  With 2-oxoglutarate as one donor, and the other dehydrogenated
    1.14.20.1
     R05301  Penicillin N + 2-Oxoglutarate + Oxygen <=> Deacetoxycephalosporin C + Succinate + CO2 + H2O
Orthology
K12744  deacetoxycephalosporin-C synthase [EC:1.14.20.1]
Other DBs
RHEA: 20751

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Ontology (1)   
   KEGG BRITE (1)   
Pathway (7)   
   KEGG PATHWAY (6)   
   KEGG MODULE (1)   
Chemical substance (7)   
   KEGG COMPOUND (7)   
Chemical reaction (3)   
   KEGG ENZYME (1)   
   KEGG RCLASS (1)   
   SABIO-RK (1)   
Gene (6)   
   KEGG ORTHOLOGY (1)   
   KEGG GENES (5)   
All databases (24)   

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